jv16 wroteHow can you know these files are in fact duplicates?
Copy usually assures they are duplicates.
In any case, as long as the "Files to find" argument is correct and "Search in" points to both locations, DFF should detect duplicates. Also, none of the "Options" should be checked.
It does on my Desk system for duplicate files on C:\ and L:\ (a USB-connected external hard drive).